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Er:YAP

當前位置: 首頁 ? Products ? 激光晶體 ? Er:YAP
Er:YAP

Er:YAP具有3μm的大發射截面,是Er:YAG的三倍大。 高摻雜的Er:YAP可以發射2.73μm 波長的激光,低摻雜的Er:YAP晶體可以發射1.66μm 的激光。Er:YAP晶體的發射光譜和激發光譜顯示出在人眼安全區域內有較寬的發射帶,其峰值在1545nm和1608nm附近,并且泵浦帶適用于常見的800nm和970nm二極管激光器,這表明YAP是一種 1.5μm人眼安全范圍內的二極管泵浦激光器的候選晶體。與YAG相比,釔鈣鈦礦鋁(YAP)由于具有較高的導熱率(~13.3 W m-1 K-1),良好的機械性能和較低的光子能量,有望成為有效激光發射的基質材料。 而且,Er:YAP是最有前途的激光材料之一,可以提供高功率的中紅外相干光束。

特點

  • 更高的熱導率
  • 較低的光子能量
  • 良好的機械性能
  • 豐富的能級結構
  • 高摻雜濃度

物理和化學特性

化學公式Er:YAlO3
晶體結構斜方晶體-Pbnm
分子質量163.884
外形半透明結晶固體
方向b軸-Pbnm
熔點1870 °C
密度5.35 g/cm3
比熱容0.557 J/g·K
導熱系數11.7 W/m·K (a-axis), 10.0 W/m·K (b-axis), 13.3 W/m·K (c-axis)
熱膨脹系數2.32 x 10-6??K-1?(a-axis), 8.08 x 10-6??K-1?(b-axis), 8.7 x 10-6??K-1??(c-axis)
精確質量163.872 g/mol
單同位素質量163.872 g/mol

光學和光譜性質

激光躍遷4S3/24I9/24I11/24I13/2
激光波長1.66 μm2.73 μm
泵浦帶0.6-0.8 μm1.53 μm
發射截面3 μm
折射率1.94-1.97 (@ 632.8 nm)

吸收和發射光譜

Er-YAP-激光晶體-南京光寶光電科技有限公司Er-YAP-激光晶體-南京光寶光電科技有限公司1

參考文獻

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[2]? Cong Q , D Sun,? Luo J , et al. 27 μm dual-wavelength laser performance of LD end-pumped Er:YAP crystal[J]. Optics Express, 2018, 26(22):28421.
[3] Hiroki, Kawase, Ryo, et al. 2.92-μm high-efficiency continuous-wave laser operation of diode-pumped Er:YAP crystal at room temperature.[J]. Optics Express, 2019.
[4] Yongjun, Dong, Jun, et al. Color centers in gamma-irradiated YAP crystals grown by the Czochralski method[J]. Physica Status Solidi, 2007.
[5] [ Miroslav Jelinek, A Klini, C Grivas,等. Deposition of Er:YAG (YAP) layers by subpicosecond and nanosecond KrF excimer laser ablation[J]. Applied Surface Science, 2002.
[6]? Dong Q ,? Zhao G ,? Cao D , et al. Growth and anisotropic spectral properties of Er:YAlO3 crystal[J]. Journal of Alloys & Compounds, 2010, 493(1-2):661-665.
[7] M Jelínek. Growth of optical waveguides by pulsed laser deposition[J]. Laser Physics, 2009, 19(2):265-273.
[8]? Cong Q , D Sun,? Luo J , et al. Growth, structure and spectroscopic properties of Er,Pr:YAP laser crystal[J]. Optical Materials, 2018, 84:59-65.
[9]? Yao W ,? Uehara H ,? Kawase H , et al. Highly efficient Er:YAP laser with 6.9 W of output power at 2920 nm[J]. Optics Express, 2020.
[10]? Remsa J ,? Jelinek M ,? Kocourek T , et al. Highly oriented crystalline Er:YAG and Er:YAP layers prepared by PLD and annealing[J]. Applied Surface Science, 2009, 255(10):5292-5294.
[11]? Basavalingu B ,? Vijaya Kumar M S ,? Girish H N , et al. Hydrothermal synthesis and characterization of rare earth doped yttrium aluminium perovskite – R:YAlO3 (R=Nd, Eu & Er)[J]. Journal of Alloys & Compounds, 2013, 552:382-386.
[12]? Perner B ,? Kvapil J ,? Kvapil J . Hydroxil and iron ions in YAP: Er laser crystals[J]. Czechoslovak Journal of Physics, 1992, 42(1):103-109.
[13]? Stankov K A ,? Hamal K ,? Jelinkova H , et al. Mode-locking of the 1.66 m transition of an Er:YAlO~3 laser[J]. OPTICS COMMUNICATIONS, 1993, 95(1):85-85.
[14] Yuchong, Ding, and,等. Near-infrared emission bands of Er3+-doped YAP and LSO crystals[J]. Journal of Luminescence, 2011.
[15]? Kawase H ,? Uehara H ,? Chen H , et al. Passively Q-switched 2.9 μm Er:YAP single crystal laser using graphene saturable absorber[J]. Applied Physics Express, 2019, 12(10):102006-.
[16]? Jelinek M ,? Klini A ,? Oswald J , et al. Properties of Er – doped layers grown from Er: YAG (YAP) crystalline targets by sub-picosecond laser deposition (p248-252)[J]. Laser Physics Letters, 2010, 1(5):-.
[17]? Yao B Q ,? Liu X L ,? Yu L X , et al. Resonantly pumped continuous wave Er:YAP laser[J]. Laser Physics, 2012, 22(4):671-672.
[18]? Nemec M ,? Jelinkova H ,? Sulc J , et al. Resonantly pumped Er:YAG and Er:YAP lasers[C]// European Conference on Lasers & Electro-optics & the European Quantum Electronics Conference Cleo Europe-eqec. IEEE, 2009.
[19]? Yao B Q ,? Liu X L ,? Yu L X , et al. Resonantly pumped multiwavelength operation in Er:YAP[J]. Laser Physics, 2012, 22(5):842-844.
[20]? Zhang B ,? Wang Y ,? Wei Z , et al. Spectroscopic properties analyses and laser characterization simulation of Er3+,Eu3+:YAP single crystal.[J]. Spectrochimica Acta Part A Molecular & Biomolecular Spectroscopy, 2018:S1386142518306115-.
[21]? Tkalcec A ,? Probst S ,? Rieger D , et al. Strong coupling of an Er3+ doped YAlO3 crystal to a superconducting resonator[J]. Phys.rev.b, 2014, 90(7).
[22] Němec, M, ?ulc, J, ?vejkar, R, et al. Temperature influence on Er:YAlO 3 spectroscopy and diode-pumped laser properties[J]. Laser Physics, 2018, 28(10).
[23] Yao,? Wen W . Thermoluminescence Properties of Doped YAP Crystals[J]. Advanced Materials Research, 2015, 1104:143-148.
[24]? Duan C K ,? Tanner P A ,? Makhov V N , et al. Vacuum ultraviolet spectra and crystal field analysis of YAlO3 doped with Nd3+ and Er3+. phys.rev.b, 2007.
[25]? Arutiunian S M ,? Kostanian R B ,? Petrosian A G , et al. A YAlO3:Er(3+)-crystal laser[J]. Kvantovaia Elektronika Moscow, 1987.

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